We can have multiple accounts under the Microsoft Outlook and the setting is similar on how the first time you have set email accounts on it.
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Below is the guideline for the process to be taken:
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Add a Microsoft Exchange account
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Emails accounts can be added when you run Outlook for the first time, or by closing Outlook, and then clicking the Mail icon in Control Panel in Windows.
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- Close Outlook.
- In Control Panel, open the Mail module.
NOTE: The Mail icon in Control Panel will not appear unless you have Outlook installed and have accessed it at leastonce. You can add an Exchange account either to a new profile that you create or to an existing profile. - Do one of the following:
Create a new profile
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A. Under Profiles, click Show Profiles.
B. Click Add.
C. In the New Profile dialog box, type a name for the profile, and then click OK.
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This is the name that you will see when starting Outlook if you configure Outlook to prompt you for a profile to use.
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Choose an existing profile
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The title bar of the Mail Setup dialog box contains the name of the current profile. To select a different profile, click Show Profiles, select the profile name, and then click Properties.
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A. Click E-mail Accounts.
B. Click New.